Copolymerization of Ethylene and Methyl Acrylate by Dibenzocycloheptyl-Substituted Aryliminopyridyl Ni(II) Catalysts
نویسندگان
چکیده
Copolymerization of ethylene with polar vinyl monomers to yield functionalized and possibly easier recyclable polyolefins is challenging it currently being pursued mainly using expensive Pd-based catalysts. Herein, the copolymerization methyl acrylate (MA) achieved by dibenzocycloheptyl-substituted aryliminopyridyl Ni(II) complexes, affording copolymers selectively in-chain incorporated MA units as well both end-of-chain inserted depending on catalyst structure reaction conditions
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ژورنال
عنوان ژورنال: Macromol
سال: 2022
ISSN: ['2673-6209']
DOI: https://doi.org/10.3390/macromol2040031